石墨烯纳米复合材料的制备及结构表征

制备了含羟基的三亚苯衍生物,2,3,6,7,10,11-六（10′-羟基癸氧基）三亚苯（HHDTP）。利用核磁共振（1H-NMR）对其结构进行了表征。通过Hummers法制备了氧化石墨（GO）。通过三亚苯基团与石墨烯片层之间强烈的π-π相互作用,在GO还原为石墨烯的过程中将HHDTP与石墨烯复合,得到了一种新型纳米复合...     

Distributed-order fractional wave equation on a finite domain. Stress relaxation in a rod

We study waves in a viscoelastic rod of finite length. Viscoelastic material is described by a constitutive equation of fractional distributed-order type with the special choice of weight functions. Prescribing boundary conditions on displacement, we obtain displacement and stress in a stress relaxation test. We use the Laplace transformation method in the time domain as a tool for solving system of differential and integro-differential equations, that describe the motion of the rod.     

铝阳极氧化膜原位偶合反应着色工艺研究

在铝阳极氧化(AAO)膜表面,通过N,N＇-二苯基丙二酰胺衍生物与取代苯基重氮盐的原位偶合反应,得到有色的取代苯偶氮N,N＇-二苯基丙二酰胺衍生物,使AAO膜呈黄色.研究结果表明,氧化膜的制作工艺为:电流密度3～3.5A/dm2 (AC),温度25～35℃,时间为1h;偶合反应的条件为:DMF为溶剂,六氢吡啶为催化剂,...     

上覆分数阶粘弹性饱和场地土位移地震放大系数

考虑土体液相和固相的耦合作用,将基岩上覆场地土视为两相饱和多孔介质。为了考虑饱和场地土的粘弹性特性,其固相土骨架的应力应变关系利用分数阶Kelvin粘弹性模型来描述,建立了上覆分数阶粘弹性饱和场地土在简谐地震波作用下的运动控制方程。运用分数导数的性质并考虑上覆场地土的边界条件和透水性条件求解了上覆分数阶粘弹性场地土在简谐地震波作用下的振动问题,得到了饱和场地土的位移地震放大系数。采用数值算例分析讨论了分数导数的阶数、液固耦合系数、土体模型参数、基岩土体剪切模量比等参数对位移地震放大系数的影响。研究结果表明,分数导数的阶数、液固耦合系数、土体模型参数、基岩土体剪切模量比对饱和场地土的地震响应有较大的影响,通过压实场地土,可以达到增大液固耦合系数减小地震响应的作用,通过增大饱和场地土的粘性和剪切模量也可以减小地震反应。     

The Effect of Gradual Fluorination on the Properties of FnZnPc Thin Films and FnZnPc/C60 Bilayer Photovoltaic Cells

Motivated by the possibility of modifying energy levels of a molecule without substantially changing its band gap, the impact of gradual fluorination on the optical and structural properties of zinc phthalocyanine (F_nZnPc) thin films and the electronic characteristics of F_nZnPc/C₆₀ (n = 0, 4, 8, 16) bilayer cells is investigated. UV–vis measurements reveal similar Q‐ and B‐band absorption of F_nZnPc thin films with n = 0, 4, 8, whereas for F₁₆ZnPc a different absorption pattern is detected. A correlation between structure and electronic transport is deduced. For F₄ZnPc/C₆₀ cells, the enhanced long range order supports fill factors of 55% and an increase of the short circuit current density by 18%, compared to ZnPc/C₆₀. As a parameter being sensitive to the organic/organic interface energetics, the open circuit voltage is analyzed. An enhancement of this quantity by 27% and 50% is detected for F₄ZnPc‐ and F₈ZnPc‐based devices, respectively, and is attributed to an increase of the quasi‐Fermi level splitting at the donor/acceptor interface. In contrast, for F₁₆ZnPc/C₆₀ a decrease of the open circuit voltage is observed. Complementary photoelectron spectroscopy, external quantum efficiency, and photoluminescence measurements reveal a different working principle, which is ascribed to the particular energy level alignment at the interface of the photoactive materials.     

基于差分自相关的运动模糊图像尺度参数识别

在运动模糊图像盲复原的过程中,对点扩散函数(PSF)进行准确识别具有非常重要的意义.当识别出运动模糊方向后,二维PSF的识别问题就可以转化成一维PSF的识别,进而提出用一阶差分自相关的方法识别运动模糊尺度.给出了差分自相关方法用于尺度识别的理论分析,重点研究和推证了在该方法下噪声对模糊尺度识别的影响,提出了改进的差分自...     

SYNTHESIS OF POLYELECTROLYTIC POLYACETYLENE DERIVATIVES BY QUATERNIZATION OF POLY(PYRIDYLACETYLENE)

Functional polyacetylenes containing pyridinium side groups (PPyA-MX, X = Br and I) were successfully synthesized. Spectroscopic techniques such as 1H-NMR, 13C-NMR, and FTIR spectroscopy were used to characterize the structure of the obtained polymers. The characterization data were well consistent with the expected macromolecular structures. PPyA-MI had good solubility in polar organic solvents and low solubility in water, while PPyA-MBr had good solubility in both polar organic solvents and water.     

重磁异常的快速均衡边界识别方法

边界识别是位场数据解释中一项重要任务,可用于资源探测等领域,是目前研究的热点问题之一。对于深部异常体目标,采用传统的边界识别方法易出现模糊、发散、变形等问题,而改进的方法大多采用高阶导数,虽然能够很好地识别出深部异常体边界,但是计算复杂,易受噪声干扰。为了改善以上问题,提出了一种稳定的快速边界识别方法,仅利用符号函数和重磁垂直导数数据,即可均衡识别不同深度的目标,且避免了高阶导数的计算。通过理论模型的实验与对比,验证了方法的便捷性、有效性、抗斜磁化能力以及抗噪能力。同时,应用实测数据验证了方法在复杂重磁环境下,能够准确清晰地分辨出异常体,可节约相关研究人员的大量时间与精力,具有很好地应用前景。     

2,3,9,10,16,17,23,24-八全氟己基钴酞菁的制备及其催化氧化乙苯

以4,5-二碘邻苯二甲腈和全氟碘己烷为原料,合成了前驱体4,5-二全氟己基邻苯二甲腈,再合成2,3,9,10,16,17,23,24-八全氟己基钴酞菁[Co Pc(C6F13)8]。前驱体结构经1HNMR、19FNMR、IR及MS表征确认,目标产物经HRMS、IR及紫外-可见吸收光谱分析确认。将其应用于氟两相体系催化乙苯氧化反应,考察其催化氧化性能,结果显示:以全氟辛烷为溶剂,催化剂用量为0.03 mmol,反应温度120℃,分子氧为氧源,反应6 h,在该条件下乙苯的转化率为41.8%,苯乙酮的选择性为85.3%。氟碳相可以回收使用5次,催化活性基本保持不变。     

酞菁类光敏剂的研究进展

酞菁类化合物是典型的近红外染料,依据有机光敏染料分子结构的设计原则,在酞菁母核的外围引入适当的取代基可以合成新型的具有特殊结构、优异光电性能的有机光敏染料。综述了酞菁类光敏染料分子的设计原则,以及具有代表性的取代金属酞菁类光敏染料的分子结构和光伏性能。